Emmanuel Dartois., Aurélie Jallat., Ivan Alata., Lisseth Gavilan., Gustavo A., Cruz-Diaz Marin Chabot., Karine Beroff., Guillermo M. Muñoz Caro. 2017. UV Photolysis of Hydrogenated Amorphous Carbons of Astrophysical Interest. Polycyclic Aromatic Compounds 37, 2-3, 94-100, 25th International Symposium on Polycyclic Aromatic Compounds (ISPAC), DOI: 10.1080/10406638.2016.1154580
In the gas phase, most of the ionized or neutral molecules detected in the interstellar and circumstellar media contain at least one carbon atom. Carbon chemistry plays thus a dominant role in the understanding of the structure and evolution of the interstellar medium (ISM). One particular zone of interest to observe small carbonaceous radicals and molecules, are the sharp molecular clouds edges exposed to energetic photons. These photon-dominated regions are rich in these hydrocarbons (like CCH, c-C3H2, C4H), and provide tests for the chemistry models in the diffuse to molecular transition. The pure gas phase models generally fail in reproducing the abundance of many of the observed species, and several authors suggest such abundances may arise from the products of the VUV photodissociation of carbonaceous grains or PAHs. Hydrogenated amorphous carbons (a-C:H or HAC), abundantly observed in the ISM, could also be at the origin of many of these small carbonaceous radicals. Experimentally, this work investigates the production and release of hydrocarbons from the VUV photolysis of a-C:H interstellar analogues under ultra-high vacuum. The experimental results are applied to a Photon Dominated Region model to constrain the impact of this release on the observed gas phase species.